Beilstein J. Nanotechnol.2014,5, 846–854, doi:10.3762/bjnano.5.96
good catalyst.
Keywords: electrocatalysis; hydrogen evolution; Sabatier’s principle; volcanocurve; Introduction
Sabatier’s principle [1] is one of the oldest rules in catalysis. For a two-step reaction passing through an adsorbed intermediate, like the hydrogen reaction, it states that the
of adsorption of hydrogen from solution should be close to zero.
If Sabatier’s principle is the only factor that governs a reaction, a plot of the reaction rate versus the free energy of adsorption of the intermediate results in a volcanocurve. Starting from a high, positive (endergonic) energy of
catalysis is scarce. In electrochemistry, Gerischer [2] and Parsons [3][4] were the first to point out that certain models for the hydrogen reaction predicted a volcano-like curve. However, it was Trasatti [5] who collected experimental data and constructed the first volcanocurve for hydrogen evolution
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Figure 1:
Trassati’s volcano plot for the hydrogen evolution reaction in acid solutions. j00 denotes the exch...